This specification covers forged low alloy and stainless steel piping components for use in pressure systems. Included are flanges, fittings, valves, and similar parts to specified dimensions or to dimensional standards.
TABLE 1 Heat Treating Requirements
|
Grade
|
Heat Treat Type
|
Austenitizing/Solutioning
|
Cooling
|
Quenching Cool
|
Tempering Temperature,
|
|
|
Temperature, Minimum
|
Media
|
Minimum or
|
|
|
|
|
or Range, °F [°C]A
|
|
Below °F [°C]
|
Range, °F [°C]
|
|
|
|
|
Ferritic-Austenitic Stainless Steels
|
|
|
|
F 50
|
solution treat and quench
|
1925
|
[1050]
|
liquid
|
500
|
[260]
|
B
|
F 51
|
solution treat and quench
|
1870
|
[1020]
|
liquid
|
500
|
[260]
|
B
|
F 52 C
|
|
|
|
liquid
|
500
|
[260]
|
B
|
F 53
|
solution treat and quench
|
1880
|
[1025]
|
liquid
|
500
|
[260]
|
B
|
F 54
|
solution treat and quench
|
1920-2060 [1050-1125]
|
liquid
|
500
|
[260]
|
B
|
F 55
|
solution treat and quench
|
2010-2085 [1100-1140]
|
liquid
|
500
|
[260]
|
B
|
F 57
|
solution treat and quench
|
1940
|
[1060]
|
liquid
|
175
|
[80]
|
B
|
F 59
|
solution treat and quench
|
1975-2050 [1080-1120]
|
liquid
|
500
|
[260]
|
B
|
F 60
|
solution treat and quench
|
1870
|
[1020]
|
liquid
|
500
|
[260]
|
B
|
A Minimum unless temperature range is listed.
B Not applicable.
C Grade F 52 shall be solution treated at 1825 to 1875 °F [995 to 1025 °C] 30 min/in. of thickness and water quenched.
DThe cooling media for Grade F 65 shall be quenching in water or rapidly cooling by other means.
TABLE 2 Chemical Requirements A
|
Identifi-
|
UNS
|
Grade
|
Composition, %
|
cation
|
Desig-
|
|
|
Carbon
|
Manga-
|
Phos-
|
Sulfur
|
Silicon
|
Nickel
|
Chromium
|
Molybde-
|
Colum-
|
Titan-
|
Other
|
Symbol
|
nation
|
|
|
|
nese
|
phorus
|
|
num
|
bium
|
ium
|
Elements
|
|
|
|
|
|
Ferritic-Austenitic Stainless Steels
|
|
|
|
|
|
|
F 50
|
S31200
|
25 chromium, 6 nickel,
|
0.03
|
2
|
0.045
|
0.03
|
1
|
5.5–6.5
|
24.0–26.0
|
1.20–2.00
|
...
|
...
|
N 0.14–0.20
|
|
|
modified with nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
S31803
|
22 chromium, 5.5
|
0.03
|
2
|
0.03
|
0.02
|
1
|
4.5–6.5
|
21.0–23.0
|
2.5–3.5
|
...
|
...
|
N 0.08–0.20
|
F 51
|
|
nickel, modified with
|
|
|
|
|
|
|
|
|
|
|
|
|
|
nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
S32950
|
26 chromium, 3.5
|
0.03
|
2
|
0.035
|
0.01
|
0.6
|
3.5–5.2
|
26.0–29.0
|
1.00–2.50
|
...
|
...
|
N 0.15–0.35
|
F 52
|
|
nickel, 1.0 molybdenum
|
|
|
|
|
|
|
|
|
|
|
|
|
S32750
|
25 chromium, 7 nickel,
|
0.03
|
1.2
|
0.035
|
0.02
|
0.8
|
6.0–8.0
|
24.0–26.0
|
3.0–5.0
|
...
|
...
|
N 0.24–0.32
|
F 53
|
|
4 molybdenum,
|
|
|
|
|
|
|
|
|
|
|
Cu 0.50
|
|
|
modified with nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
|
2507G
|
|
|
|
|
|
|
|
|
|
|
|
|
S39274
|
25 chromium, 7 nickel,
|
0.03
|
1
|
0.03
|
0.02
|
0.8
|
6.0–8.0
|
24.0–26.0
|
2.5–3.5
|
...
|
...
|
N 0.24–0.32
|
F 54
|
|
modified with nitrogen
|
|
|
|
|
|
|
|
|
|
|
Cu 0.20–0.80
|
|
|
and tungsten
|
|
|
|
|
|
|
|
|
|
|
W 1.50–2.50
|
|
S32760
|
25 chromium, 7 nickel,
|
0.03
|
1
|
0.03
|
0.01
|
1
|
6.0–8.0
|
24.0–26.0
|
3.0–4.0
|
...
|
...
|
N 0.20–0.30
|
F 55
|
|
3.5 molybdenum,
|
|
|
|
|
|
|
|
|
|
|
Cu 0.50–1.00
|
|
|
modified with nitrogen
|
|
|
|
|
|
|
|
|
|
|
W 0.50–1.00O
|
|
|
and tungsten
|
|
|
|
|
|
|
|
|
|
|
|
|
S39277
|
26 chromium, 7 nickel,
|
0.025
|
0.8
|
0.025
|
0.002
|
0.8
|
6.5–8.0
|
24.0–26.0
|
3.0–4.0
|
...
|
...
|
Cu 1.20–2.00
|
F 57
|
|
3.7 molybdenum
|
|
|
|
|
|
|
|
|
|
|
W 0.80–1.20
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
N 0.23–0.33
|
|
S32520
|
25 chromium, 6.5
|
0.03
|
1.5
|
0.035
|
0.02
|
0.8
|
5.5–8.0
|
24.0–26.0
|
3.0–5.0
|
...
|
...
|
N 0.20–0.35
|
F 59
|
|
nickel, 4 molybdenum
|
|
|
|
|
|
|
|
|
|
|
Cu 0.50–3.00
|
|
|
with nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
S32205
|
22 chromium, 5.5
|
0.03
|
2
|
0.03
|
0.02
|
1
|
4.5–6.5
|
22.0–23.0
|
3.0–3.5
|
...
|
...
|
N 0.14–0.20
|
F 60
|
|
nickel, 3 molybdenum,
|
|
|
|
|
|
|
|
|
|
|
|
|
|
modified with nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
|
2205G
|
|
|
|
|
|
|
|
|
|
|
|
|
S32550
|
26 chromium, 6 nickel,
|
0.04
|
1.5
|
0.04
|
0.03
|
1
|
4.5–6.5
|
24.0–27.0
|
2.9–3.9
|
...
|
...
|
Cu 1.50–2.50
|
F 61
|
|
3.5 molybdenum with
|
|
|
|
|
|
|
|
|
|
|
N 0.10–0.25
|
|
|
nitrogen and copper
|
|
|
|
|
|
|
|
|
|
|
|
|
|
255G
|
|
|
|
|
|
|
|
|
|
|
|
|
S32906
|
29 chromium, 6.5
|
0.03
|
0.80–1.50 0.030
|
0.03
|
0.8
|
5.8–7.5
|
28.0–30.0
|
1.5–2.6
|
...
|
...
|
Cu 0.80
|
F 65
|
|
nickel, 2 molybdenum
|
|
|
|
|
|
|
|
|
|
|
N 0.30–0.40
|
|
|
with nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
S32202
|
22 chromium, 2.0
|
0.03
|
2
|
0.04
|
0.01
|
1
|
1.00–2.80
|
21.5–24.0
|
0.45
|
...
|
...
|
N 0.18–0.26
|
F 66
|
|
nickel, 0.25
|
|
|
|
|
|
|
|
|
|
|
|
|
|
molybdenum with
|
|
|
|
|
|
|
|
|
|
|
|
|
|
nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
S32506
|
25 chromium, 6 nickel,
|
0.03
|
1
|
0.04
|
0.015
|
0.9
|
5.5–7.2
|
24.0–26.0
|
3.0–3.5
|
...
|
...
|
N 0.08–0.20
|
F 67
|
|
3 molybdenum, with
|
|
|
|
|
|
|
|
|
|
|
W 0.05–0.30
|
|
|
nitrogen
|
|
|
|
|
|
|
|
|
|
|
|
|
|
and tungsten
|
|
|
|
|
|
|
|
|
|
|
|
A All values are maximum unless otherwise stated. Where ellipses (...) appear in this table, there is no requirement and analysis for the element need not be determined or reported.
B Grade F 2 was formerly assigned to the 1 % chromium, 0.5 % molybdenum grade which is now Grade F 12.
C The present grade F 5a (0.25 max carbon) previous to 1955 was assigned the identification symbol F 5. Identification symbol F 5 in 1955 was assigned to the 0.15 max carbon grade to be consistent with ASTM specifications for other products such as pipe, tubing, bolting, welding fittings, and the like.
D Applies to both heat and product analyses.
E For Grade F22V, rare earth metals (REM) may be added in place of calcium, subject to agreement between the producer and the purchaser. In that case the total amount of REM shall be determined and reported.
TABLE 3 Tensile and Hardness RequirementsA
|
Grade Symbol
|
Tensile Strength,
min, ksi [MPa]
|
Yield Strength, min,
ksi [MPa]B
|
Elongation in 2 in.
[50 mm] or 4D,
min, %
|
Reduction of
Area, min, %
|
Brinell Hardness
Number, HBW
|
Ferritic-Austenitic Stainless Steels
|
F 50
|
100–130
|
65 [450]
|
25
|
50
|
. . .
|
|
|
[690–900]
|
|
|
|
|
|
F 51
|
90 [620]
|
65 [450]
|
25
|
45
|
. . .
|
|
F 52
|
100 [690]
|
70 [485]
|
15
|
. . .
|
. . .
|
|
F 53
|
116 [800]G
|
80 [550]G
|
15
|
. . .
|
310 max
|
|
F 54
|
116 [800]
|
80 [550]
|
15
|
30
|
310 max
|
|
F 55
|
109–130
|
80 [550]
|
25
|
45
|
. . .
|
|
|
[750–895]
|
|
|
|
|
|
F 57
|
118 [820]
|
85 [585]
|
25
|
50
|
. . .
|
|
F 59
|
112 [770]
|
80 [550]
|
25
|
40
|
. . .
|
|
F 60
|
95 [655]
|
65 [450]
|
25
|
45
|
. . .
|
|
F 61
|
109 [750]
|
80 [550]
|
25
|
50
|
. . .
|
|
F 65
|
109 [750]
|
80 [550]
|
25
|
. . .
|
. . .
|
|
F 66
|
94 [650]
|
65 [450]
|
30
|
. . .
|
290 max
|
|
F 67
|
90 [620]
|
65 [450]
|
18
|
. . .
|
302
|
|
A Where ellipses appear in this table, there is no requirement and the test for the value need neither be performed nor a value reported.
B Determined by the 0.2 % offset method. For ferritic steels only, the 0.5 % extension-under-load method may also be used.
C For sections over 5 in. [130 mm] in thickness, the minimum tensile strength shall be 70 ksi [485 MPa].
D For sections over 5 in. [130 mm] in thickness, the minimum tensile strength shall be 65 ksi [450 MPa].
E Longitudinal. The transverse elongation shall be 25 % in 2 in. or 50 mm, min.
F Longitudinal. The transverse reduction of area shall be 45 % min.
G For sections over 2 in. [50 mm] in thickness, the minimum tensile strength shall be 106 ksi [730 MPa]; the minimum yield strength shall be 75 ksi [515 MPa]